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The A 1 Σ +  u  − X 1 Σ +  g  and B 1 Π u  − X 1 Σ +  g  systems of Na 2  were excited by Ar +  and Kr +  lasers ranging from 4762 to 6471 Å . High-resolution Fourier transform spectroscopy has been used to analyze the observed spectrum. The study led to the calculation of the molecular constants of the upper A 1 Σ +  u  and B 1 Π u  states

Molecular Constants of the A 1 Σ u + and B 1 Π u States of Na 2