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Heat capacities of solid SmCl 3  and TmCl 3  were measured by differential scanning calorimetry in the ternperature range from 300 K up to the respective melting temperatures. The heat capacity of liquid SmCl 3  was also investigated. These results were compared with literature data and fitted by a polynomial temperature dependence. The temperature coefficients were given. Additionally, the enthalpy of fusion of SmCl 3  was measured. Furthermore, by combination of these results with the literature data on the entropy at 298.15 K, S 0  m (LnCl 3 , s, 298.15 K) and the standard molar enthalpy of formation of Δ form  H 0  m (LnCl 3 ,s, 298.15 K), the meruiodynaniic functions were calculated up to T = 1300 K.

Thermodynamics of SmCl 3 and TmCl 3 : Experimental Enthalpy of Fusion and Heat Capacity. Estimation of Thermodynamic Functions up to 1300K