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The self-diffusion coefficients D of the isomers of liquid N-isopropyl-N-methylacetamide (IPMAA) and acetylacetone (AC AC) are studied as functions of temperature. For AC AC also pressure dependent studies were undertaken. In IPMAA the eis and trans conformers have almost identical D. In liquid ACAC, D Kclo  is always smaller than D enol  , this difference being 15% around 300 K.

Influence of Conformational Equilibria upon the Self-Diffusion of the Conformers in Neat Liquids