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Mean amplitudes of vibration of the recently reported pentagonal bipyramidal SbF 7  2-  and BiF 7  2-  dianions were calculated from vibrational spectroscopic data, in the temperature range between 0 and 1000 K. The results are briefly discussed and some comparisons with related species are made.

Mean Amplitudes of Vibration of the Novel SbF 7 2- , BiF 7 2- and Dianions