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A vibronic band of formyl fluoride near 39,511 cm -1  has been observed using multiphoton ionisation spectroscopy. From the analysis of the partially resolved rotational structure, the rotational parameters of the (0, 2, 0, 0, 0, 0) vibrational level of an electronic state near 39,000 cm ~1 have been determined: A = 92.50(1.46) GHz and (B + C)/2 = 11.23(30) GHz. The term value was determined to be 39,510.93(30) cm -1  .

Laser Ionisation Spectroscopy Of Formyl Fluoride