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Mizuno et al. developed a jumping model to explain the nonlinear decrease of the phase transition temperature in the mixed crystals (NH 4 ) 2(1-x) K 2x Pb[Cu(NO 2 ) 6 ] with 0 ≦ x ≦ 1. Their implications and results are compared with model parameters and with the results of calculation within the Ising model with transverse field. It comes out that the assumption of a temperature independent transient time in the jumping model corresponds to the admission of tunneling in the Ising model.

Application of the Pseudo-Spin Model to the Lowest-Temperature Phase Transition of the Mixed Crystal (NH 4 ) 2(1-x) K 2x Pb[Cu(NO 2 ) 6 ]