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The luminescence of hexabenzo [be,ef,hi,kl,no,qr] coronene (I) has been studied in a perhydrocoronene matrix at temperatures from 77 to 353 K. I exhibits phosphorescence and prompt and E-type delayed fluorescence. The phosphorescence transition is symmetry-forbidden. The luminescence behaviour of I is closely related to that of coronene (II)

Fluorescence, Phosphorescence, and E-Type Delayed Fluorescence of Hexabenzo [bc,ef,hi,kl,no,qr] coronene