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For molten (Li, Na, K)Cl of the eutectic composition (53.5-8.6-37.9 mol%), in the temperature range from 773 K to 973 K the relative differences in the internal cation mobilities have been measured by the Klemm method, and the conductivity by a direct current method. From these data and the molar volumes, evaluated from those of the pure salts on the assumption of additivity, internal mobilities of the cations, b Li , b Na  and b K , have been calculated. Below ca. 873 Kt b Li  &lt; b K  &lt; b Na , and above bu b Li  &lt; b Na  &lt; b K . These orders are interpreted in terms of the potential profiles for cations located between two Cl -  ions. b Li  and b K  in the present ternary system can be fairly well expressed by function of the number density of Cl -  ions presented previously for the binary system (Li, K)Cl.

Internal Cation Mobilities in the Molten Ternary System(Li,Na,K)Cl of the Eutectic Composition