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The microwave and millimeterwave spectra of CH 3 OCl and CD 3 OCl have been investigated up to 200 GHz and centrifugal distortion constants up to the sixth order have been calculated using both Watson's 5-reduction and van Eijck-Typke operators. Watson’s determinable parameters have been obtained starting from both sets of constants.

Centrifugal Distortion Constants of Methylhypochlonte and [D 3 ]-Methylhypochlorite from the Microwave and Millimeterwave Rotational Spectra