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The IR spectra of gaseous CF 3 Cl and CF 3 Br with natural isotopic abundances have been investigated in the region 1830-1900 cm -1  with a resolution of 0.01 cm -1  or better using a Q-switched spin-flip Raman laser (SFRL). Both J and K structure of the parallel band (v 1  + v 2 ) have been resolved partly for both isotopomers of CF 3 Cl and CF 3 Br, respectively. The analysis has been performed by the usual least squares method. Additionally the J clusters of some hot bands have been observed and analyzed.

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Vibrational Spectra and Force Constants of Symmetric Tops VL [1] Spin Flip Raman Laser Spectra and Rotational Analysis of (v 1  + v 2 ) of CF 3 Cl and CF 3 Br