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A complete assignment of previously reported vibrational spectra of the TcOX 4  -  (X = Cl, Br, I) anions is proposed. Based on this assignment, force constants and mean amplitudes of vibration are evaluated and the most prominent aspects of the vibrational behaviour and structural charac­teristics of these species are discussed.

Schwingungseigenschaften der Tetrahalogenooxotechnetate (V) / Vibrational Properties of the Tetrahalogenooxotechnetates ( V)