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The measurements of the ground state spectra of both HCOF and DCOF have been extended to high-J transition. The centrifugal distortion analysis clearly showed that in HCOF the inclusion of sextic terms is absolutely necessary, whereas the effects from this source in DCOF are smaller but not negligible. The planarity condition for the sextic terms was introduced to reduce the number of parameters. Spectra in the lowest vibrational state of both HCOF and DCOF were also treated.

Analysis of Centrifugal Distortion Effects in the Rotational Spectrum of Formyl Fluoride