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The P 4 Se 3 , As 4 S 3 , As 4 Se 3  and PAs 3 S 3  molecules are supposed to have a cage-structure of the C 3V  symmetry. Normal coordinate analyses for these molecules were performed, based on a very simple initial force field transferred from P 4 S 3 . The force field was refined by adjusting the symmetry force constants to fit exactly observed frequencies. The force fields were used to calculate the mean amplitudes of vibration and Coriolis coupling constants. The standard thermodynamical functions from spectroscopic data are also given.

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Schwingungsberechnungen der käfigstrukturierten Moleküle P 4 Se 3  , AS 4 S 3 , As 4 Se 3  und PAs 3 S 3  / Molecular Vibration Analysis of the cage-like Molecules P 4 Pe 3 , As 4 S 3 , As 4 Se 3  and PAs 3 S 3