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Although the procedure to calculate the ligand field energies of terms of a many d-electron configuration in cubic symmetry is known, we present a novel semiquantitative method for the splitting of d-electron terms in cubic symmetry. The method is based on quantitative calculations of one-electron orbitals of a given angular momentum. S p littin g o f T e r m s B e y o n d a D -T e r m in a n O c ta h e d r a l L ig a n d F ield

Splitting of Terms Beyond a D-Term in an Octahedral Ligand Field