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Phosphorescence spectra and ODMR measurements at 1.3 K on a series of 13 mixed crystals of dibenzofuran (DBF) and fluorene (F) as well as of neat crystals of DBF and F (X-traps) are reported. Drastic changes in the spectra with different F:DBF ratios are observed, demonstrating the possibility of investigations of the electronic properties of F monomers, dimers, trimers and larger aggregates in this mixed crystal system of two chemically different molecules.

Triplet State Properties of Binary Mixed Crystals of Dibenzofuran and Fluorene