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The rotational spectra of the torsional excited states v̅ n  = 1 1 ,1 2 ,2 1 , 2 2 , 2 3  have been measured and assigned. The torsional fine structure was used to determine the coefficients V 3  and V'  12  of the hindering potential. For (CH 3 ) 2 O : V 3  = 2618 ± 4 cal/mole, V'12 = 18 ± 8 cal/mole, for (CD 3 ) 2 O : V 3  = 2572 ± 6 cal/mole, V' 12  = 29 ± 12 cal/mole, V 12  was correlated to V 3  .

Microwave Spectra of Dimethylether (CH 3 ) 2 O and (CD 3 ) 2 O in Excited Torsional States