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Potentiometrie measurements with asymmetric calcium-selective membranes using a three compartment flow-through cell were carried out. These membranes exhibited a behav iour which depended on their orientation with respect to the solutions. Whilst with one orientation of the membranes Nernstian behaviour was observed, in the opposite case con­ siderable asymmetry potentials appeared.

Potentiometrische Messungen an asymmetrischen calciumselektiven Membranelektroden