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Phosphorescence spectra, lifetimes and quantum yield ratios of phosphorescence and fluorescence for carbazole, dibenzo- thiophene, three dibenzo-carbazoles and the corresponding dinaphthothiophenes have been measured in ethanol and in a heavy atom matrix at 77 K. Most of the results can be explained on the basis of spin-orbit coupling and term scheme concepts but an additional phosphorescencechemical structure relation is effective in these compounds

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Phosphoreszenzeigenschaften von Dibenzo-carbazolen und strukturanalogen Dinaphtho-thiophenen / Phosphorescence Properties of Dibenzo-carbazoles and Structure-related Dinaphtho-thiophenes