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It is shown that there occur two easily distinguishable line shapes in DRM spectroscopy. These reflect the change of the integrated intensity of the signal transition when pump radiation is applied. They readily permit deductions concerning the position of the shared energy level. This result is useful for the analysis of complicated spectra, as is illustrated with examples.

Double Resonance Modulation as a Standard Technique in Microwave Spectroscopy II. Line Shape and Integrated Intensity