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The decay-curves of the excited fragments H, D, CH, and CD, produced by the impact of 250 eV-electrons on benzene and benzene-d6 , are measured in a crossed-beam-experiment. The lifetimes of the A 2  ⊿-state of CH and CD are determined to be 443 ± 5 ns. Furthermore it is found that the Balmer-lines of hydrogen as well as those of deuterium have a common decay-component, which is 77 ± 3 ns and 145 ± 5 ns in the case of H and D respectively. Because of the strong isotope effect, this behaviour is ascribed to a dissociating state of the benzene-molecule.

Das Abklingen der Balmer-Linien des Wasserstoffs nach der dissoziativen Anregung von Benzol und Benzol-D 6