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Within the study of the interaction between A and B states of As 2  molecule, a high resolution analysis of 16 absorption bands with 11 ≦ υ ≦ 17 in the A ← X system has been performed. The following constants are proposed for the A state: T 00  = 40145.9 cm -1 , ω e  = 262.7 cm -1 , ω e  x e  = 0.48 cm -1 , B e  = 0.0797 cm -1 , D e  ≅ 3 X 10 -8  cm -1  , α e  = 0.00031 cm -1  , r e  = 2.374 Å. Three new vibronic levels have been discovered in the 42 400 -44 500 cm -1  energy range, either directly or by the perturbations they induce in A levels

Absorption Spectrum of As 2 Further Analysis of the A→X System and Observation of New Electronic States