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The kinetic behavior of OH radicals was studied in the presence of a large excess of n-butane. Hydroxyl radicals were produced by pulsed vacuum-uv photolysis of H 2 O and were monitored directly by a resonance fluorescence method. The rate constant for the reaction OH + n-butane was determined to be 2.35 (±0.35) × 10 -12  cm 3  molecule -1  sec -1  at 298 °K.

Rate Constant for the Reaction of OH with n-C 4 H 10