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The general valence force constants and vibrational amplitudes have been evaluated for the metal hexahalo species of groups IV -VI elements using recent infrared and Raman spectral data. The results are employed to study the trend of variation among different species as well as the influence of cations on the relative stiffness of the chemical bonds. It has been found that the chemical bonds in the environment of a cesium cation are stronger than those of a tetraethylammonium cation.

Force Constants and Mean Amplitudes of Vibrationof the Metal-Hexahalo Species of Group IV-VI