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This paper contains further applications on symmetrical liquid mixtures of the molecular thermodynamic theory which has been developped in part I of this series. The essential feature of this theory is the superposition of "chemical" and “random” exchange equilibria between “complexes” formed by a given molecule and its z nearest neighbours, thus allowing a unified treatment of the thermodynamic phenomena in binary liquid mixtures using the equilibrium constant K of the ideal law of mass action and the energy w of pair interactions as parameters.

zeitschrift für naturforschung a

Theoretische Behandlung flüssiger Mischungen mit Hilfe von Gleichgewichtsmodellen/: Teil II. Binäre symmetrische Mischungen (Mischungsenthalpien, Dampfdrude- und Siedediagramme, Azeotropie, flüssig-flüssig-Entmischung)/ Theoretical Treatment of Liquid Mixtures by Means of Equilibrium Models