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Three methods for the measurement of the change ΔΦ of the work function Φ of a metal surface due to the presence of adsorbed particles (e. g. oxygen) have been developed utilizing the surface ionization of a beam of metal atoms (e. g. In, Sr) as a probe. The experiments have been performed with a mass spectrometer at ultrahigh vacuum.

Drei Verfahren zur Messung der Änderung der Austrittsarbeit mit Hilfe der Oberflächenionisation