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The ion-molecule reactions of thiothionylfluoride have been studied by ion cyclotron resonance spectrometry. The major secondary ions are S 2 F 3  +  , S 3 F +  , and S 3 F 2  + . In a consecutive reaction of S 3 F 2  +  the tertiary ion S 4 F 2  +  is formed. The rate constant of the IMR with the greatest yield

zeitschrift für naturforschung a

Untersuchung der Ion-Molekül-Reaktionen des Thiothionylfluorids mit Hilfe der Ionen-Cyclotronresonanz-Spektrometrie / Investigation Of Ion-Molecule Reactions Of Thiothionylfluorid By Ion Cyclotron Resonance Spectrometry