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The analysis of the proton nmr spectrum of phosphine yields a value of 94°41′ ± 3′ for the HPH bond angle. Using the microwave determined moment of inertia I B  = 6.28499 · 10 -40  g · cm 2  in connection with the nmr results an absolute value of 1.427 Å for the PH bond is calculated.

Das Protonenresonanzspektrum des Phosphorwasserstoffs in einem nematischen Lösungsmittel