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The elements of the hyperfine interaction (h.f.i.) between the manganese ion and the protons in the complex [Mn(H 2 O)6] ++  in one of the two possible sites in La 2 (Mg, Mn) 3 (NO 3 ) 12  · 24 H 2 O have been measured with ENDOR at 15 to 20 K. The six water molecules in the complex at the chosen site are equivalent for reasons of symmetry.

Ligand Hyperfine Interaction in the Complex [Mn(H 2 O) 6 ] ++ in La 2 (Mg,Mn) 3 (NO 3 ) 12 ·24H 2 O