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Relative intensities of ten previously measured metastable transitions in heptane are compared with tabulated values. The discrepancies can be explained by the different mode of observation, namely in an essentially double-focussing spectrometer as opposed to a 180° spectrometer. A detailed consideration of the influence of small amounts of energy set free in the decompositions shows that the resulting peak broadening can influence the measured peak height greatly, while the lateral broadening of the beam, due to the same energies, can be neglected. After correction for these effects the two sets of metastable intensities were found to be much better correlated.

Vergleich der Intensitäten der mit verschiedenen Methoden gemessenen Zerfälle metastabiler Molekülionen