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The loss of methyl radicals from diphenylmethyl, 1,2-diphenylethyl and stilbene ions in the mass spectrometer has been studied by means of  2 H and  13 C labelling. Mechanisms by which these methyl radicals are eliminated have been proposed.

Some Novel Eliminations of Neutral Fragments from Ions in Mass Spectrometry: Part II. Loss of Non-Terminal Carbon Atoms as Methyl Radicals