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Ternary intermetallic compound Sm 2 Ru 3 Sn 5  was synthesized in the system Sm-Ru-Sn by arc-melting and annealing at 600 °C in the field with high content of Sn. Its crystal structure was determined using single crystal X-ray diffraction data (at 240 K). The compound crystallizes in cubic system with space group  I4  ‾    3 m  (No. 217), unit cell parameter is  a  = 9.4606 (8) Å,  Z  = 4, Pearson symbol c/40. The intermetallic compound Sm 2 Ru 3 Sn 5  represents an ordered version of the centrosymmetric Ru 3 Sn 7  structure (space group  Im3  ‾m ), in which 16 f  Sn-filled crystallographic site is split into two 8 c  sites, each of which is solely occupied of one sort of atoms – Sn or Sm. The occupation of these two 8 c  sites leads to a reduction of symmetry due to the removal of the inversion center.

New compound Sm 2 Ru 3 Sn 5 with a structure derived from Ru 3 Sn 7