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We have investigated the crystal structure of the synthetic analogue of the mineral iwateite using powder diffraction and Raman spectroscopy. Na 2 BaMn(PO 4 ) 2  crystallizes in the space group  P3  ‾    $&amp;#x203e;{3}$m 1 (No. 164) with cell parameters  a  = 5.37292(1) Å, and  c  = 7.09538(1) Å ( R  wp  = 5.7%,  V  = 177.38 Å 3 ,  Z  = 1). The space group assignment is supported by the experimentally observed 11 Raman active modes which agree with the expected number of modes for the  P3  ‾    $&amp;#x203e;{3}$m 1 symmetry.

Crystal structure of the synthetic analogue of iwateite, Na 2 BaMn(PO 4 ) 2 : an X-ray powder diffraction and Raman study