English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The reaction of  bis (isocyanide)palladium complex  cis -[PdCl 2 (CNXyl) 2 ] (Xyl=2,6-Me 2 C 6 H 3 ) with excess of 4,5-dichlorobenzene-1,2-amine in a C 2 H 4 Cl 2 /MeOH mixture affords monocationic  bis (diaminocarbene) complex  cis -[PdCl C {(NHXyl)=NHC 6 H 2 Cl 2  N H 2 }{ C (NHXyl)=NHC 6 H 2 Cl 2 NH 2 }]Cl ( 3 ) in moderate yield (42%). Complex  3  exists in the solid phase in the H-bonded dimeric associate of two single charged organometallic cations and two chloride anions according to X-ray diffraction data. The Hirshfeld surface analysis for the X-ray structure of  3  reveals that the crystal packing is determined primarily by intermolecular contacts H–Cl, H–H, and H–C. The intermolecular hydrogen bonds N–H···Cl and C–H···Cl in the H-bonded dimeric associate of  3  were studied by DFT calculations and topological analysis of the electron density distribution within the framework of QTAIM method, and estimated energies of these supramolecular contacts vary from 1.6 to 9.1 kcal/mol. Such non-covalent bonding means that complex  3  is an anionic receptor for the chloride anions.

Intermolecular hydrogen bonding H···Cl in crystal structure of palladium(II)- bis (diaminocarbene) complex