English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The title compound with the nominal formula, Sr 13 Eu 8 Cd 3 Mn 1 Sb 18 , was synthesized by Sn-flux. Structure refinement was based on single-crystal X-ray diffractometer data. Employing the exact composition, the formula is Sr 13.23 Eu 7.77 Cd 3.12 Mn 0.88 Sb 18  for the solid solution Sr 21-x Eu x Cd 4-y Mn y Sb 18 . This phase adopts the Sr 21 Mn 4 Sb 18  type structure with site preferences for both Eu and Cd. The structure crystallizes in the monoclinic system in space group  C 2/ m  and  Z =4:  a =18.1522(11),  b =17.3096(10),  c =17.7691(10) Å, β=91.9638(8)°, 6632 F 2  values, 216 variables, R1=0.0254 and wR2=0.0563. Site selectivity of the elements in this new compound will be discussed in relationship with the Sr 21 Mn 4 Sb 18  type structure and other related structure types. Temperature dependent magnetic susceptibility data reveal Curie–Weiss paramagnetism with an experimental moment of 19.3 μ B /f.u. and a Weiss constant of 0.4 K. Magnetic ordering is seen at low temperatures, with a transition temperature of 3.5 K.

A new solid solution compound with the Sr 21 Mn 4 Sb 18 structure type: Sr 13 Eu 8 Cd 3 Mn 1 Sb 18