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The gallide YRh 2 Ga was synthesized by melting of the elements in an arc-furnace followed by annealing in a sealed silica tube in an induction furnace. YRh 2 Ga crystallizes with a new structure type:  P 6 3 / mmc ,  a =552.2(1),  c =3119.5(6) pm,  wR =0.0957, 497  F  2  values, and 34 variables. It is the  n =1 member of the  RE  2+ n   T  3+3 n   X  1+2 n   structure series with Laves phase (MgNi 2  type in the present case) and CaCu 5  (CeCo 3 B 2  type in the present case) related slabs in the Parthé intergrowth concept.

YRh 2 Ga – a new intergrowth variant of MgNi 2 and CeCo 3 B 2 related slabs