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Three new compounds, Cd(S 2 COMe) 2 (hmta) ( 1 ), Cd(S 2 COEt) 2 (hmta) 0.5  ( 2 ) and Cd(S 2 COiPr) 2 (hmta) ( 3 ), have been isolated from a systematic study of adduct formation between Cd(S 2 COR) 2 , R=Me, Et and iPr, precursors and potentially polydentate hmta; hmta is urotropine (hexamethylenetetramine). The compounds have been characterised by a variety of spectroscopic techniques including a photoluminescence study in both solution and the solid-state, as well as by thermal methods. Crystallography shows  1  to have μ 2 -bridging hmta leading to a one-dimensional coordination polymer. This framework is essentially repeated in  2  but with a μ 3 -bridging hmta so that Cd(S 2 COEt) 2  entities decorate the chain. By contrast, a binuclear zero-dimensional aggregate with terminally bound hmta is found in  3 . The influence of steric bulk of the alkyl substituents in Cd(S 2 COR) 2  is pivotal in determining the ultimate structural outcome.

Serendipitous compositional and structural diversity in urotropine adducts of binary cadmium xanthates