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A series of five compounds, namely [Ba( trien ) 2 ] 3 [SbSe 4 ] 2 · trien  (1)  ( trien =diethylenetriamine), [(Se 3 )Cr( en ) 2 (Se 2 )Cr( en ) 2 (Se 3 )] 2  (2)  ( en =ethylenediamine), [( pren ) 3  Eu(Te 3 ) 2  Eu( pren ) 3 ]  (3)  ( pren =1,3-diaminopropane), [( en ) 4  Ba( pren )Ba( en ) 4 ](Te 3 ) 2  (4)  and [ en H] 4 [Sn 2  Se 6 ]  (5) , which illustrate the transition of classical polychalcogenides to metalates, are presented, where mixed amine/(poly-)chalcogenide interaction with metal centers are in the focus of interest. A conventional aminothermal synthesis is discussed in comparison with ionothermal approaches. The compounds are considered useful precursors to study in situ interconversion of selenido- and telluridometalates under ionothermal conditions.

Solvothermal and ionothermal syntheses and structures of amine- and/or (poly-)chalcogenide coordinated metal complexes