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The gallide SrPdGa 3  was synthesized by melting of the elements in a sealed tantalum tube in an induction furnace. SrPdGa 3  crystallizes with a new structure type which was determined on the basis of single-crystal X-ray diffractometer data:  Cmcm ,  a =643.7(1),  b =1044.9(2),  c =600.4(1) pm,  wR =0.0283, 504  F  2  values, 19 variables. SrPdGa 3  is a new ternary ordering variant of the aristotype BaAl 4 /ThCr 2  Si 2 . The structural relation with ThCr 2  Si 2  and the closely related silicide BaNi 2  Si 2  is discussed on the basis of a group-subgroup relation. The three-dimensional [PdGa 3 ] δ–  network is dominated by Pd-Ga and Ga-Ga bonding interactions with 251–256 pm Pd-Ga and 267 pm Ga-Ga distances.

SrPdGa 3 – An orthorhombic superstructure of the ThCr 2 Si 2 type