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In this review, 260 monomeric Pt(II) complexes are summarized and analyzed in which the inner coordination sphere is built up by a pair of organomonophosphines and two chlorine atoms (PtP 2 Cl 2 ). These complexes are crystallized in four crystal systems: tetragonal (x17)&lt;orthorhombic (x31)&lt;triclinic (x90)&lt;monoclinic (x122). The square-planar environments have  cis - and  trans -configurations. The former by far prevails. The mean Pt-L bond distances ( cis - vs.  trans -configurations) are 2.347 Å (Cl,  trans  to P) and 2.230 Å (P,  trans  to Cl) vs. 2.307 Å (Cl,  trans  to Cl) and 2.320 Å (P,  trans  to P). There are two types of isomerisms:  cis -,  trans - and distortion. In general, the derivatives with a  cis -configuration are somewhat more distorted than that with a  trans -configuration.

Organomonophosphines in PtP 2 Cl 2 derivatives: structural aspects