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Application of small chiral organic molecules in catalysis has been dominated by formation of chiral enamines or iminium ions. Nucleophiles – electrophiles reactivity has been exploited in many papers. Now, the possibility to combine organocatalysis with photochemistry open new “exciting” possibilities and opportunities, in reactions that are mediated by radicals.

Stereoselective synergystic organo photoredox catalysis with enamines and iminiums