English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Poly(piperazine-amide) thin film composite (TFC) nanofiltration (NF) membranes were prepared via interfacial polymerization (IP) of trimesoyl chloride (TMC) in cyclohexane and piperazine (PIP) in water. The effect of polymerization time on the physicochemical characteristics of poly(piperazine-amide) layers and the final membrane performance was studied in detail. The morphological structures of prepared membranes were investigated using atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM). Attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), by contrast, was used to determine the chemical characteristics of the membranes. It is evident that the surface roughness increased with increasing polymerization time due to the formation of a supergranule-like structure over the interfacially synthesized poly(piperazine-amide) layer. Moreover, increasing the polymerization time led to a dramatic reduction of water permeability due to the significant increase of crosslinking poly(piperazine-amide) barrier layers. Experimentally determined data showed that the TFC NF membrane prepared at 10 s of polymerization time experienced 51.2 l/m 2 .h of water permeability with 97.02% of Na 2  SO 4  salt rejection at an operating pressure of 0.6 MPa.

journal of polymer engineering

Physicochemical characteristics of poly(piperazine-amide) TFC nanofiltration membrane prepared at various reaction times and its relation to the performance