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Oxidative degradation of 1,2-dichlorobenzene using different loadings of metal (Mn, Ni, V, and Fe) supported on CeO 2  was studied. All metal (Mn, Ni, V, and Fe) loaded CeO 2  catalysts were synthesized using the method called wet impregnation and the as-synthesized catalyst materials were characterized using different analytical instruments such as FT-IR, SEM-EDX, XRD, BET, ICP-OES, and TEM methods. The oxidation reactions of 1,2-dichlorobenzene were studied by bubbling substrate (1,2-dichlorobenzene) with ozone (0.0794 mg/L) into a glass reactor via a porous bubbler of porosity 2 over a period of 24 h. A 2.5 % Fe/CeO 2  catalyst was found to be the most active catalyst with a percentage conversion of 62 % within 24 h of ozonation. The oxidation products were identified using GC-MS and FT-IR spectroscopy was used to study the functional groups present in the ozonation product. The ozonation products that were identified are mucochloric acid and 3,4-dichloro-2,5-furandione. All the V loaded on CeO 2  catalysts produced 100 % mucohloric acid at the end of ozonation (24 h).

Ozone-initiated degradation of 1,2-dichlorobenzene over ceria-supported manganese, nickel, vanadium and iron catalysts