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C 12 H 32 O 10 Cu 2 Cl 4 , monoclinic,  P 2 1 / n  (no. 14),  a  = 9.0202(4) Å,  b  = 9.5791(4) Å,  c  = 13.6994(6) Å,  β  = 92.555(1) ° ,  V  = 1182.53(9) Å 3 ,  Z  = 2,  R   gt ( F ) = 0.0308,  wR   ref ( F   2 ) = 0.0800,  T  = 293(2) K.

The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ 2 -chloridodicopper(II) (2/1), C 12 H 32 O 10 Cu 2 Cl 4