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C 50 H 44 Cl 4 CoF 2 N 2 P 2 , orthorhombic,  Pbca  (no. 61),  a  = 18.4662(6) Å,  b  = 15.2888(5) Å,  c  = 33.2661(10) Å,  V  = 9391.9(5) Å 3 ,  Z  = 8,  R  gt ( F ) = 0.0403,  wR  ref ( F  2 ) = 0.1005,  T  = 180.0(5) K.

Crystal structure of bis[(((4-fluorophenyl)amino)methyl)triphenylphosphonium] tetrachloridocobaltate(II), C 50 H 44 Cl 4 CoF 2 N 2 P 2