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C 9 H 16 N 2 S, orthorhombic,  Pbca  (no. 61),  a  = 9.1580(4) Å,  b  = 11.8157(4) Å,  c  = 18.0202(8) Å,  V  = 1949.9 Å 3 ,  Z  = 8,  R  gt  (F)  = 0.0293,  wR  ref  (F  2  )  = 0.0838,  T  = 200 K.

Crystal structure of di(pyrrolidin-1-yl)methane-thione, C 9 H 16 N 2 S