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The previously reported Mn 0 –Mg II  bonded heterobimetallic compound [L † Mn–Mg( Mes Nacnac)] (L †  = −N(Ar † )(SiPr i  3 ), Ar †  = C 6 H 2 {C(H)Ph 2 } 2 Pr i -2,6,4;  Mes Nacnac = [(MesNCMe) 2 CH] − ; Mes = mesityl) forms an adduct complex, [L † Mn–Mg(THF)( Mes Nacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L † Mn–Mg( Mes Nacnac)] to give the hydroxide bridged heterobimetallic, [L † Mn( μ -OH) 2 Mg( Mes Nacnac)]. The Mn 0 –Mg II  bonded heterobimtallic reductively disproportionates CO 2 , affording the carbonate bridged species, [{L † Mn( μ -CO 3 )Mg(THF) ( Mes Nacnac)} 2 ], in the presence of THF. The three new compounds have been crystallographically characterized.

main group metal chemistry

X-ray crystal structures of carbonate and hydroxide bridged Mn II /Mg II  heterobimetallic complexes formed by reduction of CO 2  or H 2 O by a Mn 0 –Mg II  bonded compound