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Crystallization of [(Ph 3 Sn) 2 SeO 4 ] ⋅ 1.5H 2 O in methanol leads to the formation of [{(Ph 3 Sn) 2 SeO 4 } ⋅ CH 3 OH]  n   ( 1 ) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex  1  is arranged in polymeric zig-zag chains, composed of alternating Ph 3 Sn and SeO 4  groups. In addition, pendant Ph 3 Sn ⋅ CH 3 OH moieties are branched along chains according to a syndiotactic organization and  via  Sn-O-Se connections. From a supramolecular point of view, intermolecular hydrogen bonds established between the selenate groups (uncoordinated oxygen) and the hydroxyl functions (CH 3 OH) of the pendant groups link the chains together.

Organotin(IV) selenate derivatives – Crystal structure of [{(Ph 3 Sn) 2 SeO 4 } ⋅ CH 3 OH] n