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The polymeric organotin(IV) selenate complex [(Me 3 Sn) 3 (SeO 4 )(OH)]  n   ( 1 ) has been isolated as single crystals from the reaction of [(Me 2 NH 2 ) 2 SeO 4 ] and Me 3 SnCl in methanol. In the solid state, compound  1  was characterized by X-ray diffraction analysis, Fourier transform-infrared spectroscopy, and elemental analysis.  1  crystallizes in the orthorhombic system space group  Pbca  with  a =11.0231(2) Å,  b =16.3461(3) Å,  c =20.9945(4) Å,  α = β = γ =90°,  V =3782.89(12) Å 3 , and  Z =8. Its structure can be described as a polymeric zigzag chain based on Me 3 Sn moieties linked by tridentate selenate anions. Pendant (Me 3 Sn) 2 OH groups are also connected to the chain, according to a syndiotactic organization, and via Sn-O-Se bonds. Intermolecular OH···O hydrogen bonds and long Se-O···Sn distance interactions promote the association of chains together and lead to the propagation of a three-dimensional network. In addition, the behavior of  1  in solution (methanol) was also studied by multinuclear nuclear magnetic resonance spectroscopy and mass spectrometry.

Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative