English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Gallium(III) complexes [Ga(chmdtc) 3 ] ( 1 ) and [Ga(chedtc) 3 ] ( 2 ) (where chmdtc=cyclohexylmethyldithiocarbamate and chedtc=cyclohexylethyldithiocarbamate) have been prepared and characterized by infrared, nuclear magnetic resonance ( 1 H and  13 C) spectra, thermogravimetry, X-ray photoelectron spectroscopy, and single crystal X-ray diffraction (XRD). The thermogravimetric curves obtained for both complexes are almost similar. The final residue corresponded to gallium sulfide (Ga 2 S 3 ) above 700°C for complexes ( 1 ) and ( 2 ). In the single crystal X-ray structure of [Ga(chedtc) 3 ] ( 2 ), Ga-S bonds, and the associated C-S bonds show asymmetry as a requirement of packing. The complex shows distorted octahedral geometry due to its bite angle variations. Nano-α-Ga 2 S 3  was prepared from single source precursors [Ga(chmdtc) 3 ] ( 1 ) and [Ga(chedtc) 3 ] ( 2 ). Prepared nano-Ga 2 S 3  have been characterized by powder XRD, energy-dispersive X-ray spectroscopy technique, and transmission electron microscopy (TEM)-selected area electron diffraction analysis showing the nano-sized nature of Ga 2 S 3 . TEM micrographs confirmed the size of the particles to be 50 nm.

Synthesis and characterization of gallium(III) dithiocarbamates as suitable nano-gallium(III) sulfide precursors