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A few crystals of the title compound Te 2  Mg 2 (μ 3 -Cl 2 )(μ 2 -Cl 4 )Cl 6 (THF) 4  · CH 2  Cl 2  ( 1· CH 2  Cl 2 ) were isolated accidentally from a reaction mixture that contained the starting materials TeCl 4  and  t -BuMgCl in THF and that was recrystallized from CH 2  Cl 2 . The molecular structure of  1· CH 2  Cl 2  determined by X-ray crystallography features a rare TeCl 3  -  moiety.

Molecular structure of Te 2 Mg 2 (μ 3 -Cl 2 )(μ 2 -Cl 4 )Cl 6 (THF) 4 ·CH 2 Cl 2